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              阿伏伽德羅常數
              2010-08-20 11:29:47 來源:不詳 瀏覽:3803

              阿伏伽德羅常數

              1摩爾的任何物質所含有的該物質的微粒數叫阿伏伽德羅常數,值

              為na=6.02×1023個/摩爾

              一、生平簡介

              阿伏伽德羅(ameldeo arogadro 1776~1856)意大利自然科學家。1776年8月9日生于都靈的一個貴族家庭,早年致力于法學工作。1796年得法學博士后曾任地方官吏。他從1800年起開始自學數學和物理學。1803年發表了第一篇科學論文。1809年任末爾利學院自然哲學教授。1820年都靈大學設立了意大利的第一個物理講座,他被任命為此講座的教授,1822年由于政治上的原因,這個講座被撤銷,直到1832年才恢復,1833年阿伏伽德羅重新擔任此講座的教授,直到1850年退休。1856年7月9日在阿伏伽德羅在都靈逝世。終年80歲。

              二、科學成就

              阿伏伽德羅畢生致力于化學和物理學中關于原子論的研究。當時由于道耳頓和蓋-呂薩克的工作,近代原子論處于開創時期,阿伏伽德羅從蓋-呂薩克定律得到啟發,于1811年提出了一個對近代科學有深遠影響的假說:在相同的溫度和相同壓強條件下,相同體積中的任何氣體總具有相同的分子個數。但他這個假說卻長期不為科學界所接受,主要原因是當時科學界還不能區分分子和原子,同時由于有些分子發生了離解,出現了一些阿伏伽德羅假說難以解釋的情況。直到1860年,阿伏伽德羅假說才被普遍接受,后稱為阿伏伽德羅定律。它對科學的發展,特別是原子量的測定工作,起了重大的推動作用。

              三、趣聞軼事

              淡泊名譽,埋頭研究的人。

              阿伏伽德羅一生從不追求名譽地位,只是默默地埋頭于科學研究工作中,并從中獲得了極大的樂趣。

              阿伏伽德羅早年學習法律,又做過地方官吏,后來受興趣指引,開始學習數學和物理,并致力于原子論的研究,他提出的分子假說,促使道爾頓原子論發展成為原子——分子學說。使人們對物質結構的認識推進了一大步。但遺憾的是,阿伏伽德羅的卓越見解長期得不到化學界的承認,反而遭到了不少科學家的反對,被冷落了將近半個世紀。

              由于不采納分子假說而引起的混亂在當時的化學領域中非常嚴重,各人都自行其事,碳的原子量有定為6的,也有定為12的,水的化學式有寫成ho的,也有寫成h2o的,醋酸的化學式竟有19種之多。當時的雜志在發表化學論文時,也往往需要大量的注釋才能讓人讀懂。一直到了近50年之后,德國青年化學家邁耶爾認真研究了阿伏伽德羅的理論,于1864年出版了《近代化學理論》一書。許多科學家從這本書里,懂得并接受了阿伏伽德羅的理論,才結束了這種混亂狀況。

              人們為了紀念阿伏伽德羅,把1摩爾任何物質中含有的微粒數n0=6.02×1023mol-1,稱為阿伏伽德羅常數。

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