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              二氨基庚二酸
              2010-08-20 02:54:57 來源:不詳 瀏覽:4205

              二氨基庚二酸 diaminopimelic acid

              1949年沃克(e.work)從白喉菌(白喉棒桿菌)的水解物中發現的一種氨基酸。根據調查,除革蘭氏陽性球菌及某種鏈霉菌外,廣泛存在于幾乎所有的細菌。其含量相當于全細胞干重的0.02—0.2%,在細胞內,存在于可溶性組分及細胞壁組分等處。此外,在結核菌的可溶性蛋白質部分、抗原性脂多糖以及從枯草芽孢桿菌的芽孢提取的細胞外肽中也有所發現。其天然物無光學活性。據證明,它的生物學機能除形成穩定的細胞壁組成成分之外,在某些細菌來說(大腸桿菌、產氣桿菌),通過二氨基二庚酸脫羧酶的作用,脫羧后生成賴氨酸,成為賴氨酸生物合成的前體物質。進行生物合成時,從天冬氨酸半醛和丙酮酸首先形成吡啶羧酸,接著開環后再引入一個氨基。

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