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              有機化學人才網 | 最新人才 | 最新職位 | 技術交易 | 藥物合成
               
                 
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              乙酯殺螨醇
              2010-08-20 02:57:07 來源:不詳 瀏覽:3052

              1.物質的理化常數:

              國標編號 61876

              cas號 510-15-6

              中文名稱 乙酯殺螨醇

              英文名稱 chorobenzilate;geigy-338;ethyl 4,4'-dichlorobenzilate

              別 名 乙基-4-氯-2-(4-氯苯基)-2-羥基苯基乙酸酯;4,4'-二氯二苯乙醇酸乙酯

              分子式 (clc6h4)2c(oh)c(o)coc2h5 外觀與性狀 工業品黃色粘性液體,純品為淡黃色固體

              分子量 325.20 蒸汽壓 0.29mpa(20℃)

              熔 點 35~37℃ 點:156~158℃/9.31×10-3kpa 溶解性 幾乎不溶于水,但溶于大多數有機溶劑,包括礦物油

              密 度 相對密度(水=1)1.2816 穩定性 遇堿和強酸水解

              危險標記 15(有害品,遠離食品) 主要用途 用作農用殺蟲劑

              2.對環境的影響:

              一、健康危害

              侵入途徑:吸入、食入、經皮吸收。

              健康危害:對眼睛和皮膚有刺激作用。攝入有毒。實驗資料報道為可疑致癌物。

              二、毒理學資料及環境行為

              毒性:屬低毒類。

              急性毒性:ld50700~3100mg/kg(大鼠經口);725~4850mg/kg(小鼠經口)

              乙酯殺螨醇為致癌物,可疑致腫瘤物。

              危險特性:遇明火、高熱可燃。受高熱分解,放出有毒的煙氣。

              燃燒(分解)產物:一氧化碳、二氧化碳、氯化氫。

              3.現場應急監測方法:

              4.實驗室監測方法:

              氣相色譜法《水和有害廢物的監測分析方法》周文敏等編譯

              5.環境標準:

              食物中容許殘留限值:特定農作物2.0mg/kg(日本)

              6.應急處理處置方法:

              一、泄漏應急處理

              疏散泄漏污染區人員至安全區,禁止無關人員進入污染區,建議應急處理人員戴好防毒面具,穿化學防護服。不要直接接觸泄漏物。用砂土、干燥石灰或蘇打灰混合,收集運至廢物處理場所。用水刷洗泄漏污染區,經稀釋的洗水放入廢水系統。如大量泄漏,利用圍堤收容,然后收集、回收或無害處理后廢棄。

              二、防護措施

              呼吸系統防護:生產操作或農業使用時,應該佩戴防毒口罩。緊急事態搶救或逃生時,建議佩戴防毒面具。

              眼睛防護:戴化學安全防護眼鏡。

              身體防護:穿相應的防護服。

              手防護:戴防護手套。

              其它:工作現場禁止吸煙、進食和飲水。工作后,淋浴更衣。保持良好的衛生習慣。實行就業前和定期的體檢。

              三、急救措施

              皮膚接觸:用肥皂水和清水徹底沖洗。就醫。

              眼睛接觸:拉開眼瞼,用流動清水沖洗15分鐘。就醫。

              吸入:脫離現場至空氣新鮮處。就醫。

              食入:誤服者,飲適量溫水,催吐。就醫。

              滅火方法:泡沫、干粉、砂土。

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